| Atomic Number |
82 |
| Atomic Weight |
207.2 |
| Melting Point |
600.61 K (327.46°C or 621.43°F) |
| Boiling Point |
2022 K (1749°C or 3180°F) |
| Density |
11.342 grams per cubic centimeter |
| Phase at Room Temperature |
Solid |
Lead alloy has been known since ancient times. It is sometimes found
free in nature, but is usually obtained from the ores galena (PbS),
anglesite (PbSO4), cerussite (PbCO3) and minum (Pb3O4). Although lead
makes up only about 0.0013% of the earth's crust, it is not considered
to be a rare element since it is easily mined and refined. Most lead is
obtained by roasting galena in hot air, although nearly one third of the
lead used in the United States is obtained through recycling efforts.
Lead is a soft, malleable and corrosion resistant material. The ancient
Romans used lead to make water pipes, some of which are still in use
today. Unfortunately for the ancient Romans, lead is a cumulative poison
and the decline of the Roman empire has been blamed, in part, on lead in
the water supply. Lead is used to line tanks that store corrosive
liquids, such as sulfuric acid (H2SO4). Lead's high density makes it
useful as a shield against X-ray and gamma-ray radiation and is used in
X-ray machines and nuclear reactors. Lead is also used as a covering on
some wires and cables to protect them from corrosion, as a material to
absorb vibrations and sounds and in the manufacture of ammunition. Most
of the lead used today is used in the production on lead-acid storage
batteries, such as the batteries found in automobiles.

Lead Use by End Consumption
Several lead alloy are widely used. Solder, an alloy that is nearly
half lead and half tin, is a material with a relatively low melting
point that is used to join electrical components, pipes and other
metallic items. Type metal, an alloy of lead, tin and

antimony,
is a material used to make the type used in printing presses and plates.
Babbit metal, another lead alloy, is used to reduce friction in
bearings.
Lead forms many useful compounds. Lead monoxide (PbO), also known as
litharge, is a yellow solid that is used to make some types of glass,
such as lead crystal and flint glass, in the vulcanizing of rubber and
as a paint pigment. Lead dioxide (PbO2) is a brown material that is used
in lead-acid storage batteries. Trilead tetraoxide (Pb3O4), also known
as red lead, is used to make a reddish-brown paint that prevents rust on
outdoor steel structures. Lead arsenate (Pb3(AsO4)2) has been used as an
insecticide although other, less harmful, substances have now largely
replaced it.
Lead carbonate (PbCO3), also known as cerussite, is a white, poisonous
substance that was once widely used as a pigment for white paint. Use of
lead carbonate in paints has largely been stopped in favor of titanium
oxide (TiO2). Lead sulfate (PbSO4), also known as anglesite, is used in
a paint pigment known as sublimed white lead. Lead chromate (PbCrO4),
also known as crocoite, is used to produce chrome yellow paint. Lead
nitrate (Pb(NO3)2) is used to make fireworks and other pyrotechnics.
Lead silicate (PbSiO3) is used to make some types of glass and in the
production of rubber and paints.

Because
Lead is very soft and ductile, it is normally used commercially as Lead
Alloys. Antimony, tin, arsenic, and calcium are the most common alloying
elements. Antimony generally is used to give greater hardness and
strength, as in storage battery grids, sheet, pipe, and castings.
Antimony contents of Lead-antimony alloys can range from 0.5 to 25%, but
they are usually 2 to 5%.
Lead-Calcium Alloys have replaced Lead-antimony alloys in a
number of applications, in particular, storage battery grids and casting
applications. These alloys contain 0.03 to 0.15% Ca. More recently,
aluminum has been added to calcium-Lead and calcium-tin-Lead alloys as a
stabilizer for calcium. Adding tin to Lead or Lead alloys increases
hardness and strength, but Lead-tin alloys are more commonly used for
their good melting, casting, and wetting properties, as in type metals
and solders. Tin gives the alloy the ability to wet and bond with metals
such as steel and copper; unalloyed Lead has poor wetting
characteristics. Tin combined with Lead and bismuth or cadmium forms the
principal ingredient of many low-melting alloys.
Arsenical Lead (UNS L50310) is used for cable sheathing. Arsenic
is often used to harden Lead-antimony alloys and is essential to the
production of round dropped shot.
Lead-base bearing alloys, which are called Lead-base babbitt
metals, vary widely in composition but can be categorized into two
groups:
- Alloys of Lead, tin, antimony, and, in many instances, arsenic
- Alloys of Lead, calcium, tin, and one or more of the alkaline
earth metals
Ammunition: Large quantities of Lead alloy are used in
ammunition for both military and sporting purposes. Alloys used for shot
contain up to 8% Sb and 2% As; those used for bullet cores contain up to
2% Sb.
Terne Coatings: Long terne steel sheet is carbon steel sheet
that has been continuously coated by various hot dip processes with
terne metal (Lead with 3 to 15% Sn). Its excellent solder ability and
special corrosion resistance make the product well-suited for this
application.
Lead Foil, generally known as composition metal foil, is usually
made by rolling a sandwich of Lead between two sheets of tin, producing
a tight union of the metals.
Fusible Alloys: Lead alloyed with tin, bismuth, cadmium, indium,
or other elements, either alone or in combination, forms alloys with
particularly low melting points. Some of these alloys, which melt at
temperatures even lower than the boiling point of water, are referred to
as fusible alloys.
Anodes made of Lead Alloys are used in the electro winning and
plating of metals such as manganese, copper, nickel, and zinc. Rolled
Lead-calcium-tin and Lead-silver alloys are the preferred anode
materials in these applications, because of their high resistance to
corrosion in the sulphuric acid used in electrolytic solutions. Lead
anodes also have high resistance to corrosion by seawater, making them
economical to use in systems for the cathodic protection of ships and
offshore rigs.